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Vrstica 1:
{{v delu}}
{{chembox new
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477170210
| Name = Naftalen
| ImageFileImageFileL1 = Naphthalene-3D-balls numbering.pngsvg
| ImageSizeImageSizeL1 = 100px
| ImageNameL1 = Skeletna formula z oštevilčenimi C atomi
| ImageFileR1 = Naphthalene-from-xtal-3D-balls.png
| ImageSizeR1 = 100px
| ImageNameR1 = Model naftalena
| ImageFile2 = Naphthalene-from-xtal-3D-vdW.png
| ImageSize2 = 150px
| ImageName2 = Model naftalena
| ImageFile3 = Naphthalene-xtal-3D-vdW-B.png
| ImageSize3 = 150px
| ImageName3 = Osnovna celica kristala naftalena
| IUPACName = biciklo[4.4.0]deka-1,3,5,7,9-penten
| SystematicName = <!-- Von Baeyer nomenclature -->biciclo[4.4.0]deka-1,3,5,7,9-penten,<br>biciklo[4.4.0]deca-2,4,6,8,10-penten
| SystematicName =
| OtherNames = naftalin
| Section1 = {{Chembox Identifiers
| Abbreviations =
| CASNo = 91-20-3
| CASNo_Ref = {{cascite|correct|CAS}}
| EINECS = 202-049-5
| EINECSCASNOPubChem = 931
| PubChemChemSpiderID = 906
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| SMILES =
| UNII = 2166IN72UN| ChEBI_Ref = {{ebicite|correct|EBI}}
| InChI =
| UNII_Ref = {{fdacite|changed|FDA}}
| RTECS =
| EINECS = 214-552-7
| MeSHName =
| ChEBIKEGG = C00829
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG =
| ATCCode_prefixChEBI = 16482
| ATCCode_suffixChEMBL = 16293
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ATC_Supplemental =}}
| RTECS = QJ0525000
| SMILES = c1ccc2ccccc2c1
| InChI = 1/C10H8/c1-2-6-10-8-4-3-7-9(10)5-1/h1-8H
| InChIKey = UFWIBTONFRDIAS-UHFFFAOYAC
| StdInChI = 1S/C10H8/c1-2-6-10-8-4-3-7-9(10)5-1/h1-8H
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = UFWIBTONFRDIAS-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
| Section2 = {{Chembox Properties
| C=10|H=8
| Formula = C<sub>10</sub>H<sub>8</sub>
| Appearance = beli luskasti kristali
| MolarMass = 128,16 g/mol
| Odor = močan vonj po [[Premogov katran|premogovem katranu]]
| Appearance = trdno
| Density = 1,145 g/cm<sup>3</sup> (15,5 °C)<ref name=water.epa>{{cite web|website = http://water.epa.gov|url = http://water.epa.gov/scitech/swguidance/standards/upload/2001_10_12_criteria_ambientwqc_napthalene80.pdf|title = Ambient Water Quality Criteria for Naphthalene|publisher = United States Environmental Protection Agency|accessdate = 2014-06-21}}</ref><br> 1,0253 g/cm<sup>3</sup> (20 °C)<ref name=crc /><br> 0,9625 g/cm<sup>3</sup> (100 °C)<ref name=water.epa />
| Density = 1,15 (20<sup>o</sup>C)
| Solubility = 19 mg/L (10 °C)<br> 31,6 mg/L (25 °C)<br> 43,9 mg/L (34,5 °C)<br> 80,9 mg/L (50 °C)<ref name=crc /><br> 238,1 mg/L (73,4 °C)<ref name=chemister>{{cite web|last = Anatolievich|first = Kiper Ruslan|website = http://chemister.ru|url = http://chemister.ru/Database/properties-en.php?dbid=1&id=1005|title = naphthalene|accessdate = 2014-06-21}}</ref>
| MeltingPt = 79-82 <sup>o</sup>C
| Solubility1 = 5 g/100 g (0 °C)<br> 11,3 g/100 g (25 °C)<br> 19,5 g/100 g (40 °C)<br> 179 g/100 g (70 °C)<ref name=sioc>{{cite book|last = Seidell|first = Atherton|last2 = Linke|first2 = William F.|year = 1919|title = Solubilities of Inorganic and Organic Compounds|publisher = D. Van Nostrand Company|place = New York|edition = 2nd|pages = 443–446}}</ref>
| Melting_notes =
| Solvent1 = etanol
| BoilingPt = 218 <sup>o</sup>C
| Solubility2 = 6,8 g/100 g (6,75 °C)<br> 13,1 g/100 g (21,5 °C)<br> 31,1 g/100 g (42,5 °C)<br> 111 g/100 g (60 °C)<ref name=sioc />
| Boiling_notes =
| Solvent2 = ocetna kislina
| Solubility = 0,3 g/l (20<sup>o</sup>C)
| Solubility3 = 19,5 g/100 g (0 °C)<br> 35,5 g/100 g (25 °C)<br> 49,5 g/100 g (40 °C)<br> 87,2 g/100 g (70 °C)<ref name=sioc />
| SolubleOther =
| SolventSolvent3 = kloroform
| Solubility4 = 5,5 g/100 g (0 °C)<br> 17,5 g/100 g (25 °C)<br> 30,8 g/100 g (40 °C)<br> 78,8 g/100 g (70 °C)<ref name=sioc />
| LogP = 3.30
| Solvent4 = heksan
| VaporPressure = 0.066 hPa (20<sup>o</sup>C)
| Solubility5 = 13,6 g/100 g (6,75 °C)<br> 22,1 g/100 g (21,5 °C)<br> 131,6 g/100 g (60 °C)<ref name=sioc />
| HenryConstant =
| Solvent5 = maslena kislina
| AtmosphericOHRateConstant =
| SolubleOther = topen v alkoholih, tekočem [[amonijak]]u, [[karboksilna kislina|karboksilnih kislinah]], [[benzen]]u, [[Žveplov dioksid|žveplovem dioksidu]],<ref name=chemister /> [[ogljikov tetraklorid|ogljikovem tetrakloridu]], [[ogljikov disulid|ogljikovem disulidu]], [[toluen]]u in [[anilin]]u<ref name=sioc />
| pKa =
| pKbMeltingPtC = }}78,2
| Melting_notes = <br> {{convert|80,26|C|F K}}<br> pri 760 mmHg<ref name=crc />
| BoilingPtC = 217,97
| Boiling_notes = <br> pri 760 mmHg<ref name=water.epa /><ref name=crc />
| VaporPressure = 8,64 Pa (20 °C)<br> 23,6 Pa (30 °C)<br> 0,93 kPa (80 °C)<ref name=chemister /><br> 2,5 kPa (100 °C)<ref name=nist>{{nist|name=Naphthalene|id=C91203|accessdate=2014-05-24|mask=FFFF|units=SI}}</ref>
| LogP = 3,34<ref name=crc />
| RefractIndex = 1,5898<ref name=crc />
| HenryConstant = 0,42438 L·atm/mol<ref name=crc />
| ThermalConductivity = 98 kPa:<br> 0,1219 W/m·K (372,22 K)<br> 0,1174 W/m·K (400,22 K)<br> 0,1152 W/m·K (418,37 K)<br> 0,1052 W/m·K (479,72 K)<ref>{{cite web|title = Thermal Conductivity of Naphthalene|url = http://www.ddbst.com/en/EED/PCP/TCN_C123.php|website = http://www.ddbst.com|publisher = DDBST GmbH|accessdate = 2014-06-21}}</ref>
| Viscosity = 0,964 cP (80 °C)<br> 0,761 cP (100 °C)<br> 0,217 cP (150 °C)<ref>{{cite web|title = Dynamic Viscosity of Naphthalene|url = http://www.ddbst.com/en/EED/PCP/VIS_C123.php|website = http://www.ddbst.com|publisher = DDBST GmbH|accessdate = 2014-06-21}}</ref>
}}
| Section3 = {{Chembox Structure
| CrystalStruct = [[monoklinski kristalni sistem|monoklinska]]<ref name=sccs>{{cite book|url = http://books.google.com/books?id=hYRCAAAAQBAJ&pg=PA288|title = Structure and Chemistry of Crystalline Solids|last = Douglas|first = Bodie E.|last2 = Ho|first2 = Shih-Ming|publisher = Springer Science+Business Media, Inc.|year = 2007|isbn = 0-387-26147-8|place = New York|page = 288}}</ref>
| CrystalStruct =
| SpaceGroup = P2<sub>1</sub>/b<ref name=sccs />
| Coordination =
| PointGroup = C{{sup sub|5|2h}}<ref name=sccs />
| MolShape = }}
| LattConst_a = 8,235&nbsp;Å
| LattConst_b = 6,003&nbsp;Å
| LattConst_c = 8,658&nbsp;Å<ref name=sccs />
| LattConst_alpha =
| LattConst_beta = 122,92
| LattConst_gamma =
}}
| Section4 = {{Chembox Thermochemistry
| HeatCapacity = 165,72 J/mol·K<ref name=crc />
| DeltaHf =
| Entropy = 167,39 J/mol·K<ref name=crc /><ref name=nist />
| DeltaHc =
| DeltaHf = 78,53 kJ/mol<ref name=crc />
| Entropy =
| DeltaGf = 201,585 kJ/mol<ref name=crc />
| HeatCapacity = }}
| DeltaHc = 5156,3 kJ/mol<ref name=crc />
| Section5 = {{Chembox Pharmacology
}}
| AdminRoutes =
| Bioavail =
| Metabolism =
| HalfLife =
| ProteinBound =
| Excretion =
| Legal_status =
| Legal_US =
| Legal_UK =
| Legal_AU =
| Legal_CA =
| PregCat =
| PregCat_AU =
| PregCat_US = }}
| Section6 = {{Chembox Explosive
| ShockSens =
| FrictionSens =
| ExplosiveV =
| REFactor = }}
| Section7 = {{Chembox Hazards
| MainHazards = vnetljiv, morda rakotvoren, z zrakom tvori eksplozivne zmesi
| ExternalMSDS =
| GHSPictograms = {{GHS02}}{{GHS07}}{{GHS08}}{{GHS09}}<ref name="sigma">{{Sigma-Aldrich|id=147141|name=Naphthalene|accessdate=2014-06-21}}</ref>
| EUClass =
| EUIndexGHSSignalWord = Danger
| HPhrases = {{H-phrases|228|302|351|410}}<ref name="sigma" />
| MainHazards =
| PPhrases = {{P-phrases|210|273|281|501}}<ref name="sigma" />
| EUClass = [[Slika:Hazard X.svg|40px]] zdravju škodljivo ('''Xn''')<br>[[Slika:Hazard N.svg|40px]] okolju nevarno ('''N''')
| NFPA-H = 2
| NFPA-F = 2
| NFPA-R = 0
| NFPA-OFlashPtC = 80
| Flash_ref = <ref name="sigma" />
| RPhrases =
| SPhrasesAutoignitionPtC = 525
| Autoignition_ref = <ref name="sigma" />
| RSPhrases =
| RPhrases = {{R22}}, {{R40}}, {{R50/53}}
| FlashPt =
| SPhrases = {{S2}}, {{S36/37}}, [[S-stavki|S46]], {{S60}}, {{S61}}
| Autoignition =
| ExploLimits = 5,9%<ref name="sigma" />
| TLV-TWA = 10 ppm<ref name=crc>{{CRC90}}</ref>
| LD50 =
| TLV-STEL = 15 ppm<ref name=crc />
| PEL = }}
| LD50 = 2000 mg/kg (podgana, oralno)
| Section8 = {{Chembox Related
}}
| OtherAnions =
| OtherCations =
| OtherFunctn =
| Function =
| OtherCpds = }}
}}
 
Vrstica 161 ⟶ 180:
Več kot 400 [[milijon]]ov [[ljudje|ljudi]] je podedovalo stanje, imenovano glukoza-6-fosfat dehidrogenaze. Izpostavljenost naftalinu je bolj škodljiva za te [[ljudje|ljudi]] in lahko povzroči hemolitično [[anemija|anemijo]] pri nižjih odmerkih.
 
Na [[kitajska|Kitajskem]] je prepovedana uporaba naftalina. To je deloma posledica učinkov na [[zdravje]], kot tudi široko uporabo naravnih virov, kot je [[kafra]] za zamenjavo. Vendar pa naftalin na veliko proizvajajo v [[žoga]]h in ga trenutno izvažajo s [[Kitajska|Kitajske]] .
 
==Sklici==
{{sklici|2}}
 
== Glej tudi ==
Vrstica 172 ⟶ 194:
Naftalin (PIM 363) - predvsem o [[toksičnost]]i naftalina
 
== LiteraturaViri ==
{{Opombe}}
1. Amoore J E in Hautala E (1983). "[[Vonj]] kot pomoč za kemijsko [[varnost]]: vonj Mejne vrednosti v primerjavi z mejnimi vrednostmi in hlapnost za 214 industrijskih [[kemikalija|kemikalij]] v redčenju [[zrak]]a in [[voda|vode]]". J Appl Toksikologija 3 (6): 272-290. doi: 10.1002/jat.2550030603.
Vrstica 199 ⟶ 221:
 
13. Iskanje kitajske spletne [[trgovina|trgovine]].
 
 
 
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